Before filling the wall cavity, spray the perimeter with a 1/2-in. layer, which will expand to a 1-in. layer. These layers are called “lifts.” This will ensure that the foam penetrates any voids where the studs meet the sheathing. This also reduces the risk of bulges in the sheathing. If foam is sprayed into a large gap between the stud and the sheathing and is immediately covered by a thick layer, the pressure of the expanding foam can actually push out any sheathing that isn’t securely fastened. Wait a few minutes after picture-framing the cavity before you go back and lay down the first layer in the center of the wall.


I used this for the rim-joist in our home. A couple things: I put 1in solid core foam (cut to size) in each bay before using the spray foam. I also was able to do a relatively 'thick' spray to close off any potential gaps that may have existed. I turned off the HVAC and turned on some fans in the windows to exhaust out the fumes, and wore a mask (3m respirator).
After researching this, Im curious about a method called poor mans sprayfoam where foamboard is cut to size between studs and sprayfoamed around the perimeter. Aside from the labour doing the job yourself, the cost seems comparable, is one better than the other? What about the quality of the canned sprayfoam around the perimeter? When i see sprayfoam done, it is never a full depth of the studs, so you would get 2.5-3 inches in a 3.5" (2x4) wall. Any thoughts? 
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where to find spray foam insulation


KARNAK manufactures a complete line of sustainable roof coatings, sealants, and waterproofing solutions certified to comply with UL, FM, CRRC, ENERGY STAR®, Dade County, Title 24, and Florida’s HVZ building code. Our ENERGY STAR-labeled coatings can help buildings obtain LEED points. With four factories and seven warehouses across the U.S., KARNAK’s dedicated sales and customer service team will deliver the products you need in less time than it takes our quick-dry 535 Envirolastic to cure.
If you're chemically sensitive, it's probably not a good idea to get it installed, but it's also not a good idea to breathe musty air from the crawl space either. In addition, your house and its contents are made of lots of materials that affect your indoor air quality. If you're really concerned about this, hire a company to test your air and tell you what you can do about it. http://y2u.be/ggLAUsiuI_o
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