Typical roof coating dry film thickness vary from paint film thickness (plus or minus 3 dry mils) to more than 40 dry mils. This means a roof coating actually becomes the top layer of a composite roof membrane and underlying system. As such, the roof coating is the topmost layer of protection for the membrane, receiving the impact of sunlight (both infrared and ultraviolet (UV), rain, hail and physical damage. https://youtube.com/watch?feature=youtube_gdata&v=ggLAUsiuI_o

I have used the Froth-Pak 200 to air-seal rim joists--the area above the foundation wall in a basement. The first time I used it I did not shake the canisters well enough and the foam did not cure properly. Don't just shake the box for a few seconds. I take the tanks out of the box so I can shake/invert each tank for a minute or two. You will be able to hear the chemical sloshing around in the tanks. Also, don't ignore the recommended temperature for application--around 75 degrees F.

The problem you saw with the closed cell foam pulling away like that is due to the heat of the foam was to hot. It was actually curing out and making foam before it could adhere to the wood. The installer wasn't reading his foam correctly. He should of stopped and turned down the heat on his hose temp. Also installers have to be aware that as the sun rises and the temp in attics rises the subtrates get hotter as well. This will cause the installer to adjust his heat when installing the foam as the temp changes thru out the day.  
One of the key differentiators between traditional insulation materials and spray foam insulation is the latter’s ability to insulate and air seal. Foam insulation provides an air barrier to wherever it is applied to help mitigate air leakage from the building. Air sealing the building envelope with sprayed-in foam insulation also helps address moisture ingress to reduce the risk of mold and mildew growth as well as the formation of ice dams in colder climate zones during the winter months.  When you compare foam insulation with traditional fiberglass insulation and cellulose insulation, sprayed insulation minimizes air infiltration, it assists in limiting moisture vapor from entering and escaping the home, which in turn reduces the load on heating and cooling systems. Below is a video that compares fiberglass, cellulose and open-cell spray foam in terms of insulating and air sealing value.

Roof Spray Foam Insulation

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