once the foam is installed correctly, it is a inert plastic not much different than the foam cushions you sit on. there is not a health rick unless you have off ratio uncured foam that has not mixed properly. the foam is absolutely a health risk in its raw forms before it is mixed and cured. You should not be in the building without proper respirators and eye protection. The spray foam industry should be controlled and regulated by the same standards, testing and inspections that framing ,electrical and plumbing are. until that happens then you will have idiots with spray rigs ruining peoples homes and ruining the market for honest foam contractors that know how to price a job fairly and complete it correctly.
Water-based acrylic coatings have more than 30 years of proven performance over a wide range of substrates. It is the coating of choice for metal roofs since it is highly reflective, can be easily tinted and is not extremely slippery when damp. When used with our rust primer, even rusted roofs can be saved. TIP: If you have a metal roof or a low slope roof that doesn't pond water, consider acrylic coatings.
Steve: If your spray foam installer leaves the vents open, he will be committing the 2nd of the 4 problems I described above. You will most likely have comfort and efficiency problems. You may well have condensation problems. You will be spending a lot of money on a product that likely won't perform as it should. Don't let him leave the vents open. If the installer you've chosen doesn't understand this, you may want to choose someone else. 
If you don't have the patience to slowly fill the void with spray foam through holes drilled in one of the studs, you could (if you were an experienced carpenter) use a Sawzall to remove one of the studs and re-frame the corner as a two-stud corner. Then you could either insulate the void with a fiberglass batt or simply present the two-stud corner to the spray-foam contractor as an accessible corner.

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Yes, you're right that all of the problems mentioned above are related to the installer. I didn't try to hide that and even used the word 'installer' in two of the four headings. I can see how you'd think that the title is misleading, but in the end you can't separate spray foam insulation from its installation. Some people have the mistaken impression that if you get spray foam in your house, your home will outperform all others. My point here is that that's not true.
Johns Manville Corbond III® closed-cell spray polyurethane foam insulation offers and R-Value of R-7 per inch and can be applied in a single pass to a maximum of 3.5 inches, providing superior thermal performance with seamless air sealing and moisture control in a single step. Multiple immediate passes, with no wait time, may also be applied. With high yield and excellent adhesion, it's an ideal choice for high-performing energy efficient commercial, residential and industrial applications.
This depends on the geographic location, insulation, and cost of electricity. Lawrence Berkeley National Laboratory (LBNL), Oak Ridge National Laboratory (ORNL), National Roofing Contractors Association (NRCA), and several roofing material manufacturers have computer programs that can estimate the savings. A growing number of energy consultants are available to provide environmental regulation compliance information. http://m.youtu.be/ggLAUsiuI_o
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