Spray polyurethane foam (SPF) is a spray-applied plastic that is widely used to insulate buildings and seal cracks and gaps, making the building more energy-efficient and comfortable. SPF insulation is known to resist heat transfer extremely well, and it offers a highly effective solution in reducing unwanted air infiltration through cracks, seams, and joints.
Spray polyurethane foam, or SPF, is the main type of 2-part, closed-cell spray foam used by insulation contractors. Large-scale insulation jobs require special equipment as well as safety gear to protect the installer from chemical fumes during installation. When the foam cures and hardens just several minutes after application, it's completely safe for as long as it stays in place.

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If you don't have the patience to slowly fill the void with spray foam through holes drilled in one of the studs, you could (if you were an experienced carpenter) use a Sawzall to remove one of the studs and re-frame the corner as a two-stud corner. Then you could either insulate the void with a fiberglass batt or simply present the two-stud corner to the spray-foam contractor as an accessible corner.
For 2×4 stud walls, the fiberglass insulation will have to be split to fit. In this case, we sprayed just under 2 in. of foam (R-10.8), and split 3-1/2-in. R-13 batts in half (R-6.5) to achieve an R-17.3 insulation value. Never cram oversize batts into a wall cavity because fiberglass insulation loses R-value when it’s compressed. You could save money by spraying 1 in. of foam and adding more fiberglass, but don’t spray less than 1 in.—the foam will no longer serve as an air barrier. This particular foam creates its own vapor barrier if sprayed 2 in. thick.

To avoid the expense re-roofing a house that is simply suffering from nail fatigue, and to obtain optimum insulation, an 85mm layer of polyurethane foam can be sprayed onto the underside of the slates or tiles of a pitched roof. This stabilises and weatherproofs the roof by fixing the nails, battens and roofing felt. As the foam is a superior insulant, coupled with just 100mm of insulation at joist level, your roof will also meet the stringent thermal performance standards required for a new home. A typical roof can be insulated using the polyurethane treatment for around half the cost of re-roofing. http://www.youtube.com/watch?v=ggLAUsiuI_o&app=desktop
One of the high-tech insulation products being utilized these days is a foam-spray product called "Icynene," which is a foam that starts as two liquid components (a and b, if you will) that are heated up and sent through two hoses and meet at a tip of a gun where the magic begins. This is a thin film that expands to 100 times its volume in eight seconds, when it's permanently set up.
Global warming potential (GWP), as defined by the EPA, is a measure of how much energy the emissions of 1 ton of a gas will absorb over a given period of time, relative to the emissions of 1 ton of carbon dioxide (CO2).  Spray foam insulation products that use water as the blowing agent - typically open-cell foam however Icynene’s ProSeal Eco is a 100 percent water blown closed-cell spray foam – have a global warming potential of 1, the lowest possible number.  This is because water in the mixture reacts during the application process to release carbon dioxide and heat. The GWP of the blowing agent is that of carbon dioxide. Carbon dioxide has a GWP of 1.

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OK, Peter, I finally went back and read Alex Wilson's article on what he perceives as a serious problem. I haven't seen the full report, but based on the summary he wrote on the Green Building Advisor website, I question the science. It seems to me that he's chosen the wrong metric and he's basing his conclusion on too many assumptions because he doesn't have enough data. You can see my comments at the end of his article.
Solvent-based polyurethane coatings have excellent adhesion and when used as a base coat over asphalt, EPDM, TPO or PVC, it eliminates the need for a primer. The resulting savings on labor and material more than offsets the higher cost of the product. When top coated with silicone, it gives you the best of both worlds. It's also an excellent gutter and RV coating. https://www.youtube.com/v/ggLAUsiuI_o&feature=kp
While coatings may potentially stop minor leaks, the roof should be properly repaired and dried prior to coating application. Coatings may be able to seal pinhole leaks, which are leaks not visible to the naked eye. If the roof is leaking, the roof leak will need to be identified and repaired prior to any recoating; do not expect the coating to find and seal the leaks.
Henry 687 100% Acrylic Enviro-White Extreme Elastomeric Roof Henry 687 100% Acrylic Enviro-White Extreme Elastomeric Roof Coating is a premium high solids white reflective roof coating. It features Dirt Pick-Up Resistance (DPR) technology which prevents dirt and dust buildup keeping the roof whiter and more reflective longer. When cured it forms a permeable membrane which prevents liquid infiltration ...  More + Product Details Close

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I live in Baton Rouge LA with a very old and drafty house. There is no blockages in the walls between the crawl space and attic. Lots of critters just come on in. I would like to used closed cell sprayed under house to warm up floors and block moisture. I would like to spray closed cell into attic, but am afraid of enclosing attic due to moisture build-up. Can I spray closed cell against the attic floor in same way as installing bats, thus leaving my venting the same as it always has been. Other ideas? Thanks. http://www.youtube.com/e/ggLAUsiuI_o
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