Allison--would be very interested in your take on the GHG issues of foams, which have received lots of smart commentary recently. To highlight a few: architect Jesse Thompson's comments on Tom's Good vs Bad post on Energy Circle, the very thorough piece by Alex Wilson on Green Building Advisor and Michael Anschel's cautionary diatribe on Remodeling. 
Note:  A board foot is defined as a 12" x 12" square at 1" thick. Actual output can be affected by a number of factors including temperature and humidity. The theoretical yield has become an industry standard for identifying certain sizes of two component kits. Theoretical yield calculations are performed in perfect laboratory conditions, without taking into account the loss of blowing agent or the variations in application methods and types.
Before you decide on spray foam or another method of insulation, it's important to understand the superiority of spray foam compared to traditional materials. When compared to fiberglass batts, spray foam offers nearly double the R-value per inch, achieves air-sealing and insulation in one step, won't be damaged by mold or moisture, and won't settle, compress, or otherwise be damaged to the point it needs replacement.
Polyurethane is a closed-cell foam insulation material that initially contains a low-conductivity gas in its cells.[5] As a result of the high thermal resistance of the gas, spray polyurethane insulation typically has an initial R-value around R-3.4 to R-6.7 per inch.[5] In comparison, blown fiberglass typically has an R-Value of only R-3 to R-4 per inch.[6]
It also has a great waterproofing ability that can shield the roof’s membrane from water and moisture damage. You can also count on the liquid roof coating for its outstanding performance for a wide range of applications and uses. This product can be used at tears and seams as well as in sealing air conditioners and venting systems and anywhere else where rubberized coating is needed.

Spray Foam Roof Insulation