Today’s “third generation” of blowing agents have a GWP of 700 to 1000 which is still remarkably high considering water/CO2 has a GWP of 1. However, innovation from some chemical manufacturers like the Chemours Company have introduced the next generation of HFO blowing agents such as Opteon 1100, which significantly reduces the GWP impact when using closed-cell spray foam insulation products.
However, coating asphalt shingles and built-up composition roofs requires more caution. The National Roofing Contractors Association’s (NRCA) director of technical services has stated "The roofing industry is aware of a number of issues that could have negative consequences for field application of coatings over asphalt shingle roof systems. Anyone considering this type of application should be aware of the concerns so they can weigh them against the benefits claimed in coating product promotional materials."[2]

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Spray foam is a very specialized packing material, often required for use in shipping valuable fragile items. Engineered packaging principles are designed to protect sculptures, vases, large fossils, lamp bases, busts, computers, furniture, chandeliers and other objects of unusual shape. By virtue of the liquid foam expanding by up to 30-60 times the volume of its liquid state, it efficiently protects almost any size, form and weight.

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Here's a simpler, less expensive alternative: Cut some 2-inch-thick rigid-foam insulation and glue it to the subfloor between the joists or support it with nails driven partway into the joists. Then fill any gaps between the edges of the foam boards and the joists using the canned spray foam sold at home centers or hardware stores. An even easier option is to nail the foam panels against the bottom edge of the joists and seal the joints with canned foam, but you'll lose some headroom and access to any pipes and wires between the joists. As with spray-foam kits, protect yourself and the floor from the dripping globs of canned foam. A full face shield, gloves, and a hat would be a good start.

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Spray polyurethane foam (SPF) is a spray-applied plastic that is widely used to insulate buildings and seal cracks and gaps, making the building more energy-efficient and comfortable. SPF insulation is known to resist heat transfer extremely well, and it offers a highly effective solution in reducing unwanted air infiltration through cracks, seams, and joints. http://www.youtube.com/watch?feature=youtu.be&v=ggLAUsiuI_o
This depends on the geographic location, insulation, and cost of electricity. Lawrence Berkeley National Laboratory (LBNL), Oak Ridge National Laboratory (ORNL), National Roofing Contractors Association (NRCA), and several roofing material manufacturers have computer programs that can estimate the savings. A growing number of energy consultants are available to provide environmental regulation compliance information. http://m.youtu.be/ggLAUsiuI_o
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