OK, Peter, I finally went back and read Alex Wilson's article on what he perceives as a serious problem. I haven't seen the full report, but based on the summary he wrote on the Green Building Advisor website, I question the science. It seems to me that he's chosen the wrong metric and he's basing his conclusion on too many assumptions because he doesn't have enough data. You can see my comments at the end of his article.

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Jennifer, I'm not an expert on the health effects of closed cell foam. A lot of people live in houses with closed cell foam and have no health problems from it, at least not short-term, acute problems. I do know of one person who had it removed from her crawl space because she was convinced it caused her dog to get sick, but I know only what she told me.  
We are turning our roof into an unvented roof assembly by raising the roof and blowing in SPF. We are planning to leave the existing vapor barrier down but remove the fiberglass batting and then adding 6" of SPF in all the cavities, to completely seal and insulate the house. Should we have any concerns about doing it "upside down" and not spraying the foam directly to the underside/sheathing of the roof?

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What do you mean by "our AC units require fresh air ventilation"? Fresh air doesn't come from the attic. If there's an atmospheric combustion appliance in the attic, such as an 80 AFUE furnace, then you shouldn't be encapsulating the attic anyway. If that's the case, you don't want spray foam on the roofline at all. You can either change out the furnace to a sealed combustion unit or do your insulating and air-sealing at the flat-ceiling level.
Johns Manville Corbond® Open-cell Appendix X Spray Foam provides an R-Value of R-3.7 per inch, and meets AC 377 NFPA 286 Appendix X requirements for application without an ignition barrier in attics and crawl spaces. This low-density, nonstructural insulation allows for high yield while prodiving excellent heat, air and sound control.   Recommended for use in residential, commercial and industrial applications. 

Today’s “third generation” of blowing agents have a GWP of 700 to 1000 which is still remarkably high considering water/CO2 has a GWP of 1. However, innovation from some chemical manufacturers like the Chemours Company have introduced the next generation of HFO blowing agents such as Opteon 1100, which significantly reduces the GWP impact when using closed-cell spray foam insulation products.

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Acrylic coatings are typically applied in two coats, with the second running perpendicular to the first. 1 gallon per 100 square feet is a good estimate for these coatings, as they do not need to be applied nearly as thick as many other coatings. These coatings can be sprayed or roll-applied. Acrylic coatings generally require a re-coat within 2-3 years of application.

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If your foam pulled away just a little bit, Jamie, and they were able to fix it with just a little bit of touching up, then it wasn't as bad as the house where I saw this problem. As the last photo above shows, it had pulled away significantly from the studs and rafters, and it was all over the house. This was closed cell foam, and interestingly, it didn't pull away from the horizontal framing members, just the vertical and sloped ones. They did some touch up, but that wasn't enough. I don't know how this one ended up getting resolved. I think maybe the contractor came back and sprayed cellulose on top of the foam.
That’s $58.3 Billion dollars. That’s roughly how much money we wasted in 2010 in the US according to the Department of Energy because of air leaking out of our building envelopes. If your building leaks energy, you’re paying more for energy than you need to. Clearly you’re not alone. If you’re ready to claim your share of the savings, it’s quicker and easier than you think.
Spray polyurethane foam (SPF) is a spray-applied plastic that is widely used to insulate buildings and seal cracks and gaps, making the building more energy-efficient and comfortable. SPF insulation is known to resist heat transfer extremely well, and it offers a highly effective solution in reducing unwanted air infiltration through cracks, seams, and joints. http://www.youtube.com/watch?feature=youtu.be&v=ggLAUsiuI_o
There should be a foam sill sealer between the bottom plate and the concrete foundation wall. But voids in the wood or concrete, or tears in the sill sealer, can create gaps where air and insects can penetrate. While you’re sealing the rim board, cover the bottom plate and top off the concrete as well. There’s no need to picture-frame the joist spaces before filling them, but don’t spray a lift more than 2 in. thick.
As this example illustrates, it's important to seal the envelope completely. One of spray foam's biggest selling points is its air-sealing ability, but it can't seal places where it's not sprayed. One of the nice things about using spray foam in new construction is that you can do a Blower Door test before the drywall goes in. Even better, you can test for leaks with a fog machine. https://www.youtube.com/v/ggLAUsiuI_o?version=3
Even if you use Liquid EPDM Roof, be sure to check your roof periodically for leaks. If you leave your roof in rough condition or bad repair, you could be in for huge problems and costly repairs. Your entire coach is beneath your roof. When repairing leaks and general waterproofing, the Liquid EPDM Roof coatings is the least expensive and most effective choice. That’s the facts about Liquid EPDM Roof and its benefits. It's a money-saving, environmentally friendly alternative.
The insulation at eaves level will leave your loft area comfortable for use and free from condensation. By installing the insulation at rafter level, it keeps the loft void warmer and prevents condensation build-up, which can otherwise occur when increasing insulation at ceiling level. The warmer, drier, cleaner roof space eliminates the risk of pipes and tanks freezing. http://www.youtube.com/watch?feature=youtube.be&v=ggLAUsiuI_o
RE: my June 12 post...We went ahead and had the attic sprayed with a Soy-based product. Stayed in a hotel for 3 nites. Still smelled a little bad but that's gone away over time. I'm very glad we didn't use the other foam as even that much outgassing of a petrochemical could have sent my wife to the hospital. Unfortunately, the spray crew didn't speak English(at least not to me) and were kinda lazy, so they ended up spraying over some can fixtures from the kitchen below that were not insulation-contact rated. So I hired an electrician to come out, pull down the cans, pull out what he thought was an appropriate amount of foam to create a big enough air space and then re-install the cans. I billed the firm for the electrician plus an extra night we had to stay in the hotel and they paid, no questions asked. Guess they knew they had screwed up.  

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Barrier’s specially-trained technicians have applied over 5 million square feet of coatings in a wide variety of commercial, industrial and residential settings throughout the United States. With our experience, product knowledge and long list of satisfied customers, Barrier is uniquely qualified to give your enterprise the protection it deserves.  

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Spray polyurethane foam (SPF) is a spray-applied plastic that is widely used to insulate buildings and seal cracks and gaps, making the building more energy-efficient and comfortable. SPF insulation is known to resist heat transfer extremely well, and it offers a highly effective solution in reducing unwanted air infiltration through cracks, seams, and joints. https://www.youtube.com/watch?v=ggLAUsiuI_o&feature=share
If you cut the nails holding one of the corner studs to the bottom plate and the top plate with a Sawzall, you can use a flat bar (or a flat bar plus a wrecking bar) to pull the stud off the sheathing nails. Either re-use the stud, or buy a new stud, and install the stud with toenails as shown in the link I provided in Comment #51 (this link: Outside corner detail).
You’ll have to install a new tip every time you stop spraying for more than 30 seconds because the foam will set inside the nozzle and clog it. Spray foam kits come with extra tips, but it’s still important to (1) clear the room of everything that could get in the way, (2) decide which areas you’ll spray first, (3) put ladders wherever you need them, and (4) set up a fan or two to vent the fumes outdoors.

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There are several types of reflective roof coatings that impart varied reflectance rates/ values. Typically, the reflective coatings are what are commonly referred to as white coatings and there are also aluminum coatings typically used with asphalt. Highly reflective white roof coatings are typically comprised of acrylics, urethanes, silicones, SBS, SEBS, and other types. http://www.youtube.com/v/ggLAUsiuI_o&feature=kp
The guys who sprayed my attic were trained and certified, but I later found out, too late, that they had no experience and my attic was the first they'd ever sprayed. I was also never told to vacate my house for any length of time, and so I (and my pets) were in the house the day they sprayed and the entire time the off ratio foam was filling my home with horrendous vapors. The company kept telling me that it was a good job and I had nothing to worry about, even after I'd had 2 other experienced sprayers from 2 different companies visually examine the foam and confirm that large areas appeared to be off ratio. The 3rd sprayer from yet another company, was also outraged because the company who did my attic had failed to vacuum up all of the old cellulose insulation, and he also noticed areas where the foam was shrinking or pulling away, and this was not even 5 weeks after the spraying.   https://youtube.com/e/ggLAUsiuI_o
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