Spray foam insulation, when properly installed is both an air barrier and when closed cell foam is used at the proper depth a vapor barrier!  Before hiring any contractor you should establish the brand of foam being used and verify that with the named manufacture.  Please ask for ESR reports and MSDS sheets on any foam being installed in your home. A couple areas where you might consider spray foam insulation include:
A. You can use closed-cell spray foam that way if you want, although you should realize that the spray foam will prevent the roof sheathing from drying inward. This approach should only be used if the roof sheathing is bone dry, because it will never dry when sandwiched in this manner. Most building scientists would prefer to see fiberglass rather than closed-cell spray foam under the roof sheathing in this type of assembly.
Heatlok Soy 200 Plus®, is our high-performing, versatile spray foam insulation for commercial and residential construction. Our unique formula incorporates recycled plastic bottles and renewable oils to create our high-performing, closed-cell spray foam insulation. Heatlok Soy 200 Plus has a high R-value of 7.4 at 1 inch, and a density of two pounds. This polyurethane insulation combines multiple control layers into a single application, saving both time and money in construction costs. With our innovative technology, Heatlok Soy 200 Plus is developed with 14 % renewable and recycled content, and is the ideal choice for commercial, residential, and multi-family construction.

Spray polyurethane foam (SPF) is a spray-applied plastic that is widely used to insulate buildings and seal cracks and gaps, making the building more energy-efficient and comfortable. SPF insulation is known to resist heat transfer extremely well, and it offers a highly effective solution in reducing unwanted air infiltration through cracks, seams, and joints. http://www.youtube.com/watch?feature=youtu.be&v=ggLAUsiuI_o
Ames® Roof Coatings are premium elastomeric coatings that seal out moisture, renew old surfaces and even save energy. We have products specifically formulated for all types of roofs including; Wood, Tar, Metal, Rolled Roofing, EPDM Rubber, Foam and many other surfaces. Ames’ coatings form a waterproof seal to preserve and protect your roof. Our white roof coatings reflect sunlight, substantially reducing roof temperatures. Ames® products are environmentally friendly, waterbase, non-toxic, VOC-free and water cleanup.

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Before filling the wall cavity, spray the perimeter with a 1/2-in. layer, which will expand to a 1-in. layer. These layers are called “lifts.” This will ensure that the foam penetrates any voids where the studs meet the sheathing. This also reduces the risk of bulges in the sheathing. If foam is sprayed into a large gap between the stud and the sheathing and is immediately covered by a thick layer, the pressure of the expanding foam can actually push out any sheathing that isn’t securely fastened. Wait a few minutes after picture-framing the cavity before you go back and lay down the first layer in the center of the wall.

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In the early days of insulating attics, people believed the insulation was a heat source. That’s not the case, as the insulation is actually a barrier between two areas of different temperatures. As for the “hot roof” theory, the unvented attic system could make the temperature of the roof go up a little, but this increase won’t cause damage to your shingles.

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Spray polyurethane foam, or SPF, is the main type of 2-part, closed-cell spray foam used by insulation contractors. Large-scale insulation jobs require special equipment as well as safety gear to protect the installer from chemical fumes during installation. When the foam cures and hardens just several minutes after application, it's completely safe for as long as it stays in place.
Though foam insulation has a higher upfront cost than fiberglass or cellulose, it recoups this expenditure in a relatively short period of time. Additionally, the insulation’s permanence means that it will continue to generate savings over the life of your structure. The durability of this insulation means that you can rest easy in the knowledge that at least one component of your structure will stand the test of time.
Repair and seal roof penetrations, tears, open seams, etc. using Elastek 103 Crack & Joint Sealant and reinforce with polyester roof fabric as necessary. In larger or deep ponding areas, apply Elastek 500 Puddle Plaster to fill in areas that hold water. Avoid using plastic roof cement. Serious ponding should be referred to a roofing contractor. Blisters in previous coatings may be opened but these areas must be allowed to dry-out completely. Blisters in the roofing ply should be left alone unless likely to break. Caulk and reinforce open seams, roof penetrations, cracks, and tears. These are potential leak points so work carefully and thoroughly. Use fabric to build flashings around roof edges or roof penetrations, and to reinforce various coating repairs. A polyester fabric is used because it will stretch with the coatings. (Fiberglas fabric is not recommended.) Fabric is normally cut to extend three inches beyond the repaired area in all directions. The coating is applied to the roof surface and the fabric is immediately pushed into the wet surface. An additional coat is applied over the fabric and the patch is allowed to dry. If your roof has stucco parapets, examine them for cracks along the sides and top. These areas often permit water to enter the wall and can cause blisters and wrinkles in the roof surface. Repair with Elastek 103 Crack & Joint Sealant. If you do not have parapets, examine the metal drip edge for a tight seal with the roof membrane. Use 4″ or 6″ roofing fabric covered under and over with Crack & Joint Sealant to seal cracks along drip edges, penetrations, and open seams.
Here's a simpler, less expensive alternative: Cut some 2-inch-thick rigid-foam insulation and glue it to the subfloor between the joists or support it with nails driven partway into the joists. Then fill any gaps between the edges of the foam boards and the joists using the canned spray foam sold at home centers or hardware stores. An even easier option is to nail the foam panels against the bottom edge of the joists and seal the joints with canned foam, but you'll lose some headroom and access to any pipes and wires between the joists. As with spray-foam kits, protect yourself and the floor from the dripping globs of canned foam. A full face shield, gloves, and a hat would be a good start.

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As an industry leader in high performance building products, we were the first in the world to commercialize the latest state-of-the-art spray foam insulation technology. Our corporate headquarters in Houston, TX is home to multiple laboratories, customer care, technical services and a world class manufacturing plant that produces spray foam and elastomeric roof coatings. We are constantly striving to raise the bar in energy efficiency and sustainable building practices.

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Roof Coatings should not be confused with deck coatings. Deck coatings are traffic bearing - designed for waterproofing areas where pedestrian (and in some cases vehicular) traffic is expected. Roof coatings will only waterproof the substrates but will not withstand any kind of on going use by people or vehicles (such as walkways, patios, sundecks, restaurants, etc.).
Although spray polyurethane foam has many advantages over other types of insulation, spray foam installation isn’t foolproof. Some builders have reported problems with sloppy foam insulation. For example, some installers have been known to begin spraying before the chemical components are up to temperature, which can affect component mixing and foam performance. When components are poorly mixed, or mixed in the wrong ratio or at the wrong temperature, cured foam has been known to shrink away from rafters or studs, leaving cracks. Some installers rush through their spraying, resulting in voids.
To avoid the expense re-roofing a house that is simply suffering from nail fatigue, and to obtain optimum insulation, an 85mm layer of polyurethane foam can be sprayed onto the underside of the slates or tiles of a pitched roof. This stabilises and weatherproofs the roof by fixing the nails, battens and roofing felt. As the foam is a superior insulant, coupled with just 100mm of insulation at joist level, your roof will also meet the stringent thermal performance standards required for a new home. A typical roof can be insulated using the polyurethane treatment for around half the cost of re-roofing.

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My project was a 2 part one.  First the guest house was to be used for an elderly couple with some health issues.  The idea of using chemicals which can be harmful to the respiratory track has made me change my mind about proceeding. The guest house was single story with a low attic height and 600 square feet and the main house (part 2)  is 2,800 sq feet. After reading the comments below, I would like a quote from someone that uses a soy product that is non toxic. .  
Ames® Roof Coatings are premium elastomeric coatings that seal out moisture, renew old surfaces and even save energy. We have products specifically formulated for all types of roofs including; Wood, Tar, Metal, Rolled Roofing, EPDM Rubber, Foam and many other surfaces. Ames’ coatings form a waterproof seal to preserve and protect your roof. Our white roof coatings reflect sunlight, substantially reducing roof temperatures. Ames® products are environmentally friendly, waterbase, non-toxic, VOC-free and water cleanup.

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The problem was that the installer was doing his first spray foam job ever, and the thickness of the insulation varied from zero (visible roof deck) to about 9". Unfortunately, good average thickness doesn't cut it. The coverage needs to be uniform because a lot of heat will go through the under-insulated areas. (See my article on flat or lumpy insulation performance.) https://m.youtube.com/embed/ggLAUsiuI_o
Heavy-duty fibered repair mastic designed to patch roof Heavy-duty fibered repair mastic designed to patch roof surfaces. Use in wet or dry conditions to seal and stop leaks around flashings skylights vent pipes chimneys and valleys. Wet-R-Dri roof cement is ideal for the repair of cracks seams and holes in all roofing materials. It is also excellent for ...  More + Product Details Close

I don't know if it's common or uncommon, but installing a layer of rigid foam above your roof sheathing in order to interrupt thermal bridging is always a good idea, and is preferable in all respects to a roof assembly without any rigid foam above the sheathing. If you decide to install rigid foam above the roof sheathing, you shouldn't use closed-cell spray foam under the sheathing; either use open-cell spray foam (which is vapor-permeable) or a fluffy insulation like cellulose, mineral wool, or fiberglass (any of which will allow the roof sheathing to dry to the interior).

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Get the Power to Seal & Insulate Perfectly in Just 5 Minutes. The Foam it Green Promise: 1>Simpler, Easier, Faster Spray Foam 2>No Special Skills or Know How 3>Professional Results or Better Saves You Time, Money and Hassles. Delivers to your door, ready to use. Just follow the simple instructions. Saves Energy with High R-value Closed Cell Foam. R-Value of 7 in Just 1 Inch. Provides a seamless air barrier in 1 step. This Kit Provides Approx. 602 Square Feet at 1” thickness of cured foam. Class I E-84 Fire-Retardant Foam that meets building code specs. This Anti-Microbial Formula passed the stringent ASTM G-21 test for preventing mold growth on the surface of the foam. Includes everything you need to complete your project. Weighs 120 lbs, including steel canisters pressured with nitrogen. Orders with multiple kits on it may ship via LTL instead of UPS. The LTL carrier calls to arrange a convenient delivery time. Usually Ships Same Business Day. See Manufacturer for returns and warranty policy.
Sporadic cases of hypersensitivity pneumonitis (HP) have also been reported in workers exposed to isocyanates. The symptoms may seem like the flu, with fever, muscle aches, and headaches. Other symptoms may include a dry cough, chest tightness, and difficult breathing. Individuals with chronic HP often experience progressively more difficult breathing, fatigue, and weight loss. Individuals with acute HP typically develop symptoms 4–6 hours after exposure.[4]
John Manville's complete line of spray polyurethane foam (SPF) insulation solutions provides superior thermal energy efficiency, as well as advanced air and sound control. SPF insulation completely covers gaps and voids, works in hard-to-insulate areas and can exceed the performance of traditional fiberglass insulation. Both Johns Manville SPF product categories, open-cell and closed cell, deliver high yield, superior performance and exceptional sprayability.

I recently did a remodel project for my basement using spray foam insulation. The original builder has used fiberglass, but I wanted the best insulation i could find. We chose closed cell foam because it blocks moisture from getting into the house. It took one day to install and was fumey for about 3 hours. It was pretty cool watching it being done. It comes out as a liquid and then expands rapidly into a foam. It's quick! Then they took a types of saw to shave it flat with the wall studs so we could then go ahead and drywall.

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Liquid Roof is a specially formulated version of Liquid Rubber that has the flexibility needed for vehicles that are traveling and causing significant amounts of tension as it travels and turns. If your RV is stationary the entire year you can order the Liquid Rubber but if you do travel with your RV you will need to purchase the Liquid Roof. Note applying the Liquid Rubber over an RV will void its warranty. 

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If you're chemically sensitive, it's probably not a good idea to get it installed, but it's also not a good idea to breathe musty air from the crawl space either. In addition, your house and its contents are made of lots of materials that affect your indoor air quality. If you're really concerned about this, hire a company to test your air and tell you what you can do about it. http://y2u.be/ggLAUsiuI_o
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