I am an Architect in Toronto. I am designing a new roof addition to a row house building. Because of existing conditions and the shape of the new roof. It may be easiest to use closed cell spray foam within the areas of the joists. My question is when spray foam is used in this situation do I need to worry about how the joist members may be thermal bridges? It is not common to provide a little bit of rigid insulation to protect the joist members? The additional layer of outboard insulation will require an extra layer of plywood above the insulation which will add to cost.
Thoroughly clean the roof surface. Roofs collect oils from asphalt, chimneys, and cars plus lots of dirt and dust. Coatings don’t stick well to any of these. We recommend cleaning with an inexpensive solution of TSP or TSP Substitute in a bucket of water (follow label instructions). Use a broom to scrub ponding areas and areas of peeling coatings. Work a section at a time and hose off the dirty water. Sweep away puddles to promote drying. Do not allow wash water to dry on walls, furniture, windows, and visible surfaces.  https://youtube.com/e/ggLAUsiuI_o
Allison--would be very interested in your take on the GHG issues of foams, which have received lots of smart commentary recently. To highlight a few: architect Jesse Thompson's comments on Tom's Good vs Bad post on Energy Circle, the very thorough piece by Alex Wilson on Green Building Advisor and Michael Anschel's cautionary diatribe on Remodeling. 
One thing I wanted to mention was that I think your price point is a little high and that might deter people from considering spray foam. As a project manager for a spray foam company for years I can tell you that we offer 0.5 Lb. open-cell foam at around $.25/board foot. We even offer a 1.0 Lb. open-cell foam for less/the same cost as you quoted the 0.5 Lb. foam for above. The 1/0 Lb. open-cell foam has an R-value of almost 5.
Henry 587 Dura-Brite White Elastomeric Roof Coating is Henry 587 Dura-Brite White Elastomeric Roof Coating is a premium high solids formula offering better weather protection solar reflectivity and longevity than economy grade reflective roof coatings. Cured coating forms a permeable membrane which prevents liquid infiltration but allows moisture vapor to vent or breathe out of underlying substrate. Recommended ...  More + Product Details Close

How Much Will Spray Foam Save Me

Spray foam insulation is a great product. Homes insulated with it can be some of the most efficient and comfortable homes built. I've been in plenty of these homes and can tell you that when spray foam is installed properly, they outperform 99% of fiberglass batt-insulated, stick-built homes. (I can also tell you that 73% of all statistics are made up on the spot, so please don't ask for documentation of that statistic.) http://youtube.com/watch?v=ggLAUsiuI_o&app=desktop
Typical roof coating dry film thickness vary from paint film thickness (plus or minus 3 dry mils) to more than 40 dry mils. This means a roof coating actually becomes the top layer of a composite roof membrane and underlying system. As such, the roof coating is the topmost layer of protection for the membrane, receiving the impact of sunlight (both infrared and ultraviolet (UV), rain, hail and physical damage. https://youtube.com/watch?feature=youtube_gdata&v=ggLAUsiuI_o
Although spray polyurethane foam has many advantages over other types of insulation, spray foam installation isn’t foolproof. Some builders have reported problems with sloppy foam insulation. For example, some installers have been known to begin spraying before the chemical components are up to temperature, which can affect component mixing and foam performance. When components are poorly mixed, or mixed in the wrong ratio or at the wrong temperature, cured foam has been known to shrink away from rafters or studs, leaving cracks. Some installers rush through their spraying, resulting in voids. http://www.youtube.com/watch?feature=youtu.be&v=ggLAUsiuI_o

When choosing a waterproofing and sealing product, we must see to it that we can easily use and apply it using simple tools, including a squeegee or a paint roller. With ease of application, we can be certain that we can achieve hassle-free application and smoother and more attractive finish than other products could give. So when reviewing the products we have featured above, we have made sure that they are easy to apply.

Roof Coating