There are several types of reflective roof coatings that impart varied reflectance rates/ values. Typically, the reflective coatings are what are commonly referred to as white coatings and there are also aluminum coatings typically used with asphalt. Highly reflective white roof coatings are typically comprised of acrylics, urethanes, silicones, SBS, SEBS, and other types. https://youtube.com/v/ggLAUsiuI_o?version=3
The drawback to spray foam insulation is it's been known to cause certain health issues such irritation of the eye and the gastrointestinal and respiratory tracts. Direct contact can cause inflammation to the skin, and some individuals have been known to break out in a rash on the arms, chest and neck area. Spray foam insulation has also been linked to a few cases of hypersensitivity pneumonitis. This condition can cause:

Silicone coatings are typically produced by adding a catalyst and solvents to a silicone base. Because the silicone is a natural material, these coatings are bio-degradable. They can be applied to a roofing system using many different techniques, including spraying or rolling. Silicone coatings are available in many colors, including reflective white and translucent.
Polyurethane Spray Foam Insulation is used in industries ranging from mining to movies, from cold storage to marine flotation. Spray Foam Insulation’s ability to seal out air and insulate quickly means it’s always in high demand for residential and commercial applications. Spray Foam Insulation is critical for solving our nation’s energy challenges because it dramatically reduces the energy needed to heat and cool our homes and offices.

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Never spray foam on a surface with a moisture level of more than 20 percent—the foam won’t stick. If the surface you’re spraying hasn’t been exposed to water for a few weeks, it should be OK to spray. But if you’re patching a wall that recently sustained water damage, or was just assembled with new, wet lumber, you may want to test the moisture level before you spray. You can get a moisture meter here.
I recently did a remodel project for my basement using spray foam insulation. The original builder has used fiberglass, but I wanted the best insulation i could find. We chose closed cell foam because it blocks moisture from getting into the house. It took one day to install and was fumey for about 3 hours. It was pretty cool watching it being done. It comes out as a liquid and then expands rapidly into a foam. It's quick! Then they took a types of saw to shave it flat with the wall studs so we could then go ahead and drywall.

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I have been looking to have closed cell insulation added through out my attic space. I cant seam to find a installed that wants to install no more than 2 inches, and thats not near my R-valve for South Carolina (Lake Greenwood)please send any advice that will help me to see what installer will perform the correct job. This is a expense that i can only afford to do once. Sandi
Here's a simpler, less expensive alternative: Cut some 2-inch-thick rigid-foam insulation and glue it to the subfloor between the joists or support it with nails driven partway into the joists. Then fill any gaps between the edges of the foam boards and the joists using the canned spray foam sold at home centers or hardware stores. An even easier option is to nail the foam panels against the bottom edge of the joists and seal the joints with canned foam, but you'll lose some headroom and access to any pipes and wires between the joists. As with spray-foam kits, protect yourself and the floor from the dripping globs of canned foam. A full face shield, gloves, and a hat would be a good start.

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The guys who sprayed my attic were trained and certified, but I later found out, too late, that they had no experience and my attic was the first they'd ever sprayed. I was also never told to vacate my house for any length of time, and so I (and my pets) were in the house the day they sprayed and the entire time the off ratio foam was filling my home with horrendous vapors. The company kept telling me that it was a good job and I had nothing to worry about, even after I'd had 2 other experienced sprayers from 2 different companies visually examine the foam and confirm that large areas appeared to be off ratio. The 3rd sprayer from yet another company, was also outraged because the company who did my attic had failed to vacuum up all of the old cellulose insulation, and he also noticed areas where the foam was shrinking or pulling away, and this was not even 5 weeks after the spraying.   https://youtube.com/e/ggLAUsiuI_o
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