OK, Peter, I finally went back and read Alex Wilson's article on what he perceives as a serious problem. I haven't seen the full report, but based on the summary he wrote on the Green Building Advisor website, I question the science. It seems to me that he's chosen the wrong metric and he's basing his conclusion on too many assumptions because he doesn't have enough data. You can see my comments at the end of his article.

It also has a great waterproofing ability that can shield the roof’s membrane from water and moisture damage. You can also count on the liquid roof coating for its outstanding performance for a wide range of applications and uses. This product can be used at tears and seams as well as in sealing air conditioners and venting systems and anywhere else where rubberized coating is needed.

SPF insulation applied by professionals is usually described as either a high- or low-pressure foam and is available as either open- or closed-cell. Each type has advantages and disadvantages depending on the application requirements. The comparison chart below can be helpful in explaining or understanding which type of SPF insulation is best suited to a specific application.
We are turning our roof into an unvented roof assembly by raising the roof and blowing in SPF. We are planning to leave the existing vapor barrier down but remove the fiberglass batting and then adding 6" of SPF in all the cavities, to completely seal and insulate the house. Should we have any concerns about doing it "upside down" and not spraying the foam directly to the underside/sheathing of the roof? http://www.youtube.com/watch?v=ggLAUsiuI_o
I'm in the process of redoing my basement and read through the posts. I took out one inch styrofoam covered by 1/4 " beadboard and installed 2X4s and plan on putting in fiberglass batts between them(r-13) with 1/2 in drywall over top of that. Do you think I will see a significat increase in heat control? Should I have done more?... it's a little after the fact, but still curious to know if I will see a big difference based on your experience. https://www.youtube.com/watch?v=ggLAUsiuI_o&feature=youtu.be
Most closed-cell spray foam is now formed using hydrofluorocarbon (HFC) blowing agents that have high global warming potential, partially or completely offsetting the climate benefits of the energy savings they can offer. In the United States, HFCs are scheduled to be phased out by January, 2021. A few spray foam suppliers have started supplying spray foam blown with hydrofluoroolefin (HFO) blowing agents without this problem as of early 2017.[14] https://www.youtube.com/watch?v=ggLAUsiuI_o&feature=kp

We service the entire Central Texas Area including Waco, Abilene, Fort Worth, as well as Granbury, Aledo, Weatherford, Eastland, Hico, Hamilton, Brownwood, Comanche, Glen Rose, Meridian, Cleburne, Mineral Wells, Graham, Breckenridge, Decatur, Eastland, Ranger, Gorman. We have done work as far away as Colorado, so don't hesitate to call if you're outside this immediate area.
I used this for the rim-joist in our home. A couple things: I put 1in solid core foam (cut to size) in each bay before using the spray foam. I also was able to do a relatively 'thick' spray to close off any potential gaps that may have existed. I turned off the HVAC and turned on some fans in the windows to exhaust out the fumes, and wore a mask (3m respirator).

Spray Foam Basement Ceiling

Spray foam insulation, also known as foaming insulation or sprayed insulation, is a two-part liquid insulation material that insulates and air seals wherever it is applied. The material comes in two large 55 gallon drums – an iso and a resin. These two liquids are kept separate until applied at the jobsite by a qualified, licensed spray foam installer. The two liquids travel up through a heated hose to the spray gun where they are combined to create the foam. The foam expands within seconds to fill the cavity surface.  Depending on the type of sprayed-in foam insulation used, closed-cell or open-cell, the foam expands between 40 and 100 times its size upon application. 
once the foam is installed correctly, it is a inert plastic not much different than the foam cushions you sit on. there is not a health rick unless you have off ratio uncured foam that has not mixed properly. the foam is absolutely a health risk in its raw forms before it is mixed and cured. You should not be in the building without proper respirators and eye protection. The spray foam industry should be controlled and regulated by the same standards, testing and inspections that framing ,electrical and plumbing are. until that happens then you will have idiots with spray rigs ruining peoples homes and ruining the market for honest foam contractors that know how to price a job fairly and complete it correctly.
During colder months, 2 component foam is very sensitive to temperature variances. Per product instructions, both tank temperatures need to be above 70°F (21°C) for at least 24 hours prior to use. All application surfaces should be clean/dry and above 60°F (16°C) prior to application. Variance outside of the recommended temperature can affect foam yield and performance.

How Much Spray Foam Garage