Spray foam is a very specialized packing material, often required for use in shipping valuable fragile items. Engineered packaging principles are designed to protect sculptures, vases, large fossils, lamp bases, busts, computers, furniture, chandeliers and other objects of unusual shape. By virtue of the liquid foam expanding by up to 30-60 times the volume of its liquid state, it efficiently protects almost any size, form and weight.
Liquid Rubber is generally fine when applied in one coat at a 20 mil film (42 sq ft per gallon) thickness and will still withstand extremes. That is the beauty of the EPDM polymer. A second coat would provide insurance where exposures are likely to be very extreme. Radical extremes in temperature where constant surface temperatures reach 250°F or above or -20°F or below. Warning, though, if the second coat is applied at the wrong time, it may create cracking, fissures or bubbling. The second coat should be applied either when the first coat is still tacky or when that first coat has had a chance to fully cure (up to 3 months.) https://youtube.com/v/ggLAUsiuI_o?version=3
Check with the coating manufacturer who may be able to suggest applicators who have used their products and have familiarity with the application. Another option would be to interview contractors and ask specific questions about their proven ability to install roof coatings. Contractors affiliated with the National Roofing Contractors Association (NRCA) or local roofing contractor trade associations typically are more knowledgeable. Consult those groups’ websites for contractors.
If you're chemically sensitive, it's probably not a good idea to get it installed, but it's also not a good idea to breathe musty air from the crawl space either. In addition, your house and its contents are made of lots of materials that affect your indoor air quality. If you're really concerned about this, hire a company to test your air and tell you what you can do about it.
One of the key differentiators between traditional insulation materials and spray foam insulation is the latter’s ability to insulate and air seal. Foam insulation provides an air barrier to wherever it is applied to help mitigate air leakage from the building. Air sealing the building envelope with sprayed-in foam insulation also helps address moisture ingress to reduce the risk of mold and mildew growth as well as the formation of ice dams in colder climate zones during the winter months. When you compare foam insulation with traditional fiberglass insulation and cellulose insulation, sprayed insulation minimizes air infiltration, it assists in limiting moisture vapor from entering and escaping the home, which in turn reduces the load on heating and cooling systems. Below is a video that compares fiberglass, cellulose and open-cell spray foam in terms of insulating and air sealing value.