If you don't have the patience to slowly fill the void with spray foam through holes drilled in one of the studs, you could (if you were an experienced carpenter) use a Sawzall to remove one of the studs and re-frame the corner as a two-stud corner. Then you could either insulate the void with a fiberglass batt or simply present the two-stud corner to the spray-foam contractor as an accessible corner.

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Rust-Oleum® 780 Elastomeric Roof Coating provides a high initial reflectivity value of 85%, energy efficiency, long term durability and excellent resistance to weathering and dirt pick-up. This elastomeric roof coating is formulated to meet and/or exceed the standards established in ASTM D 6083. Rust-Oleum 780 Elastomeric Roof Coating waterproofs and weatherproofs metal, weathered single ply membranes as well as smooth surface asphalt built-up and modified bitumen roofing substrates. http://www.youtube.com/v/ggLAUsiuI_o&feature=youtube_gdata
For 2×4 stud walls, the fiberglass insulation will have to be split to fit. In this case, we sprayed just under 2 in. of foam (R-10.8), and split 3-1/2-in. R-13 batts in half (R-6.5) to achieve an R-17.3 insulation value. Never cram oversize batts into a wall cavity because fiberglass insulation loses R-value when it’s compressed. You could save money by spraying 1 in. of foam and adding more fiberglass, but don’t spray less than 1 in.—the foam will no longer serve as an air barrier. This particular foam creates its own vapor barrier if sprayed 2 in. thick.

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For large jobs, professionals such as Dr. Energy Saver use two-part foam, which comes in larger containers. With 2-part spray foam, it's necessary to mix separate resin and catalyst compounds at the application nozzle. Combining these ingredients starts a chemical reaction that creates expanding foam. Contractors use small 2-part foam "kits" to air-seal an attic or to seal and insulate ductwork. To insulate an entire attic or wood-framed wall with spray foam, the resin and catalyst compounds are pumped to the application nozzle from 50-gallon drums in a specially equipped truck.

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Always wait a few minutes before spraying additional lifts, and never spray a lift more than 2 in. thick. The foam needs time to cure before being covered with another lift. Uncured foam results in reduced R-values. The allowable thickness of lifts varies by manufacturer, but all have a limit. The two most common spray foam installation mistakes are failing to wait for lifts to cure and spraying lifts that are too thick.
Sealection 500 is a spray-applied adhesive, which once applied, expands in place using water-blown technology, without CFCs, HCFCs, or ozone-depleting chemicals. Unlike traditional fiberglass insulation, Sealection 500 will maintain its performance; time and temperature have no effect on the spray foam insulation's R-value of 3.81 at 1 inch. Sealection 500 never deteriorates or decomposes. The product retains its shape and half-pound density over time, and never settles or compacts. http://youtube.com/v/ggLAUsiuI_o
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