Allison--would be very interested in your take on the GHG issues of foams, which have received lots of smart commentary recently. To highlight a few: architect Jesse Thompson's comments on Tom's Good vs Bad post on Energy Circle, the very thorough piece by Alex Wilson on Green Building Advisor and Michael Anschel's cautionary diatribe on Remodeling. 
A. You can use closed-cell spray foam that way if you want, although you should realize that the spray foam will prevent the roof sheathing from drying inward. This approach should only be used if the roof sheathing is bone dry, because it will never dry when sandwiched in this manner. Most building scientists would prefer to see fiberglass rather than closed-cell spray foam under the roof sheathing in this type of assembly.
Spray foam insulation is typically priced by volume, meaning your cost will depend on how much material you need to use to insulate your space, although other factors may influence price as well. In most cases, the cost of spray foam insulation is more than worth it, as it's a once and done upgrade that will not only provide energy savings in your home, but also improve your home's overall comfort.
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Our commitment to using intelligent solutions and high-performing, quality products to help solve global environmental challenges is evident in both the use of renewable and recycled content in our products, as well as our green recognitions and certifications by various organizations, such as the NAHB Research Center, LEED Certifications, and USDA Bio-Preferred, just to name a few.
I used this product to seal and insulate my rim joists as I am finishing the basement. The builder used R13 batt insulation when we built the house 3 years ago. I use a dehumidifier to control moisture in the basement which is below grade. The setting I use is 55%. The dehumidifier kicks on periodically and requires emptying every few days. Since using the foam all around the house on the rim joists and sill plate, the dehumidifier has stayed at 50% for over two weeks since spraying and rarely turns on anymore. I also put the original R13 batt insulation back up after the foam cured.

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The roof must be thoroughly cleaned, and allowed to dry thoroughly. This is a critical step to ensure a successful coating application. Be careful not to damage the lap seams. Care should be taken when pressure washing not to disturb the integrity of the underlying roof membrane particularly where there are adhered seams. Refer to the specific coating manufacturer you are using for their specific requirements for roof preparation.
Heatlok Soy 200 Plus®, is our high-performing, versatile spray foam insulation for commercial and residential construction. Our unique formula incorporates recycled plastic bottles and renewable oils to create our high-performing, closed-cell spray foam insulation. Heatlok Soy 200 Plus has a high R-value of 7.4 at 1 inch, and a density of two pounds. This polyurethane insulation combines multiple control layers into a single application, saving both time and money in construction costs. With our innovative technology, Heatlok Soy 200 Plus is developed with 14 % renewable and recycled content, and is the ideal choice for commercial, residential, and multi-family construction.
Liquid Roof is a specially formulated version of Liquid Rubber that has the flexibility needed for vehicles that are traveling and causing significant amounts of tension as it travels and turns. If your RV is stationary the entire year you can order the Liquid Rubber but if you do travel with your RV you will need to purchase the Liquid Roof. Note applying the Liquid Rubber over an RV will void its warranty.

These coatings are emulsified asphalt and consist of asphalt particles dispersed in water; they utilize clay as the emulsifying component. These coatings also contain many types of organic and/or inorganic fibers and fillers to provide extra strength to the coating. These coatings are available in black, brown, or as a reflective coating when titanium dioxide or aluminum pigments are added.
Foam is very sticky; you'll need to wear disposable coveralls with a hood, and gloves, a face mask, and eye protection. It takes some practice to spray foam evenly and, because it expands so dramatically, to control its depth; 2 inches is all you need to seal the joist cavities. You need a clear area so that you can work without interruption; any pause longer than 30 seconds will clog the nozzle and require putting on a new one. It's also critical that the air temperature stays between 75 and 85 degrees.
Ames® Roof Coatings are premium elastomeric coatings that seal out moisture, renew old surfaces and even save energy. We have products specifically formulated for all types of roofs including; Wood, Tar, Metal, Rolled Roofing, EPDM Rubber, Foam and many other surfaces. Ames’ coatings form a waterproof seal to preserve and protect your roof. Our white roof coatings reflect sunlight, substantially reducing roof temperatures. Ames® products are environmentally friendly, waterbase, non-toxic, VOC-free and water cleanup.

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For 2×4 stud walls, the fiberglass insulation will have to be split to fit. In this case, we sprayed just under 2 in. of foam (R-10.8), and split 3-1/2-in. R-13 batts in half (R-6.5) to achieve an R-17.3 insulation value. Never cram oversize batts into a wall cavity because fiberglass insulation loses R-value when it’s compressed. You could save money by spraying 1 in. of foam and adding more fiberglass, but don’t spray less than 1 in.—the foam will no longer serve as an air barrier. This particular foam creates its own vapor barrier if sprayed 2 in. thick.

I used this product to seal and insulate my rim joists as I am finishing the basement. The builder used R13 batt insulation when we built the house 3 years ago. I use a dehumidifier to control moisture in the basement which is below grade. The setting I use is 55%. The dehumidifier kicks on periodically and requires emptying every few days. Since using the foam all around the house on the rim joists and sill plate, the dehumidifier has stayed at 50% for over two weeks since spraying and rarely turns on anymore. I also put the original R13 batt insulation back up after the foam cured.
Porch urns are an excellent way to add seasonal curbside flair. However, tall items such as twigs, birch stems or even pumpkins can sway in the breeze and make a mess of your carefully planned decor. To prevent things from shifting, place your items in the container and spray around them with expanding foam to create a comfy nest that will keep your urns looking great. Place a layer of moss, hay or greenery on top to finish the look.

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Most closed-cell spray foam is now formed using hydrofluorocarbon (HFC) blowing agents that have high global warming potential, partially or completely offsetting the climate benefits of the energy savings they can offer. In the United States, HFCs are scheduled to be phased out by January, 2021. A few spray foam suppliers have started supplying spray foam blown with hydrofluoroolefin (HFO) blowing agents without this problem as of early 2017.[14]

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I used this for the rim-joist in our home. A couple things: I put 1in solid core foam (cut to size) in each bay before using the spray foam. I also was able to do a relatively 'thick' spray to close off any potential gaps that may have existed. I turned off the HVAC and turned on some fans in the windows to exhaust out the fumes, and wore a mask (3m respirator).
OK, Peter, I finally went back and read Alex Wilson's article on what he perceives as a serious problem. I haven't seen the full report, but based on the summary he wrote on the Green Building Advisor website, I question the science. It seems to me that he's chosen the wrong metric and he's basing his conclusion on too many assumptions because he doesn't have enough data. You can see my comments at the end of his article.
My project was a 2 part one.  First the guest house was to be used for an elderly couple with some health issues.  The idea of using chemicals which can be harmful to the respiratory track has made me change my mind about proceeding. The guest house was single story with a low attic height and 600 square feet and the main house (part 2)  is 2,800 sq feet. After reading the comments below, I would like a quote from someone that uses a soy product that is non toxic. .  
The guys who sprayed my attic were trained and certified, but I later found out, too late, that they had no experience and my attic was the first they'd ever sprayed. I was also never told to vacate my house for any length of time, and so I (and my pets) were in the house the day they sprayed and the entire time the off ratio foam was filling my home with horrendous vapors. The company kept telling me that it was a good job and I had nothing to worry about, even after I'd had 2 other experienced sprayers from 2 different companies visually examine the foam and confirm that large areas appeared to be off ratio. The 3rd sprayer from yet another company, was also outraged because the company who did my attic had failed to vacuum up all of the old cellulose insulation, and he also noticed areas where the foam was shrinking or pulling away, and this was not even 5 weeks after the spraying.   https://youtube.com/e/ggLAUsiuI_o
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